| 세션명 | Virtual Lightning Session |
|---|---|
| 발표장 | Online (10/20~10/22) |
| 논문코드 | VPS-38 |
| 발표일 | --2020 |
| 발표시간 | |
| 논문제목 | Tunable Photonic Microspheres of Comb-Like Supramolecules |
| 발표자 | Yi Yang |
| 발표자 소속 | Huazhong University of Science and Technology |
| 저자 | Yi Yang, Tae-Hui Kang1, Gi-Ra Yi1,†, Jintao Zhu† |
| 소속 | Huazhong University of Science and Technology; 1Sungkyunkwan University |
| 논문초록 | Photonic crystals (PCs) are ideal candidates for reflective color pigments with high color purity and brightness due to tunable optical stop band. Herein, the generation of PC microspheres through 3D confined supramolecular assembly of block copolymers (polystyrene-block-poly(2-vinylpyridine), PS-b-P2VP) and small molecules (3-n-pentadecylphenol, PDP) in emulsion droplets is demonstrated. The intrinsic structural colors of the PC microspheres are effectively regulated by tuning hydrogen-bonding interaction between P2VP blocks and PDP, where reflected color can be readily tuned across the whole visible spectrum range. Also, the effects of both PDP and homopolymer (hPS) on periodic structure and optical properties of the microspheres are investigated. Moreover, the spectral results of finite element method (FEM) simulation agree well with the variation of structural colors by tuning the periodicity in PC microspheres. The supramolecular microspheres with tunable intrinsic structural color can be potentially useful in the various practical applications including display, anti-counterfeit printing and painting. |
THE POLYMER SOCIETY OF KOREA